Conditional equilibrium constants in multicomponent heterogeneous adsorption: The conditional affinity spectrum
نویسندگان
چکیده
منابع مشابه
Conditional equilibrium constants in multicomponent heterogeneous adsorption: the conditional affinity spectrum.
The concept of conditional stability constant is extended to the competitive binding of small molecules to heterogeneous surfaces or macromolecules via the introduction of the conditional affinity spectrum (CAS). The CAS describes the distribution of effective binding energies experienced by one complexing agent at a fixed concentration of the rest. We show that, when the multicomponent system ...
متن کاملConditional Swap Regret and Conditional Correlated Equilibrium
We introduce a natural extension of the notion of swap regret, conditional swap regret, that allows for action modifications conditioned on the player’s action history. We prove a series of new results for conditional swap regret minimization. We present algorithms for minimizing conditional swap regret with bounded conditioning history. We further extend these results to the case where conditi...
متن کاملAffinity distribution functions in multicomponent heterogeneous adsorption. Analytical inversion of isotherms to obtain affinity spectra.
An analytical approach for the interpretation of multicomponent heterogeneous adsorption or complexation isotherms in terms of multidimensional affinity spectra is presented. Fourier transform, applied to analyze the corresponding integral equation, leads to an inversion formula which allows the computation of the multicomponent affinity spectrum underlying a given competitive isotherm. Althoug...
متن کاملCONDITIONAL EXPECTATION IN THE KOPKA'S D-POSETS
The notion of a $D$-poset was introduced in a connection withquantum mechanical models. In this paper, we introduce theconditional expectation of random variables on theK^{o}pka's $D$-Poset and prove the basic properties ofconditional expectation on this structure.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2006
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.2162876